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Peptides modification by genetic code expansion Natural proteins are synthesized from 20 canonical amino acids, and this limited and conservative repertoire of amino acids significantly restricts the diversity and complexity of protein structures and functions

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Our structure identified an unpredicted non-peptide agonist-binding pocket in which reorganization of extracellular loop 3 and transmembrane helices 6 and 7 manifests independently of direct ligand interaction within the deep transmembrane domain pocket

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