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doi: 10.1016/j.ccr.2008.05.005 8 De MartinoMRathmellJCGalluzziLVanpouille-BoxC

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The question of whether peptides expire has a clear answer: yes, and using degraded peptides for neurological applications is not just wasteful but potentially counterproductive

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Interestingly, we found that efficient phase transfer from water to dichloromethane only occurs in the pH range of 6.09.6, at which the amine groups in DDA are protonated (positively charged) and the carboxylic acid groups in GSH are deprotonated (negatively charged) supporting the electrostatic nature of the HIP in DDA-GSH-AuNCs (Fig